Through comparing the drying dynamics of the FBMS, the small rod-shaped crystals with a mean size of 9.6 μm produced by ultrasonic irradiation can be completely desolvated within 20 h, while the desolvation time of long needle crystals with an average size of about 157 μm obtained by direct cooling/antisolvent crystallization and seeding crystallization processes is more than 80 h. Thus the crystal size and morphology were found to be the key factors affecting the desolvation kinetics and the smaller size produced by using ultrasound can benefit the intensification of the drying process. Overall, the ultrasound-assisted crystallization showed a full improvement including crystal properties and process efficiency during the preparation of fotagliptin benzoate desolvated crystals.Several studies have reported the release of halogenated persistent organic pollutants (POPs) and polycyclic aromatic hydrocarbons (PAHs) associated with open burning of municipal solid waste. Considering soil as a sink for such organic contaminants, we conducted an in-depth study on the surface soil concentrations of polychlorinated dibenzo-p-dioxins/furans (PCDD/Fs), polychlorinated biphenyls (PCBs) and sixteen USEPA enlisted PAHs collected from thirteen zones of the two major municipal dumpsites, Kodungaiyur dumpsite (KDS) and Perungudi dumpsite (PDS) of Chennai city. Indigenous microbes from dumpsite soil samples were isolated and identified based on 16S rRNA sequencing and phylogenetic analysis. Using indigenous microbes, we have elucidated the bioavailability of the targeted organic pollutants for each site.Range of Σ17PCDD/Fs, Σ25PCBs and ∑16PAHs varied between 3.96-612 pg/g (96.0 pg/g; median), ND-182 ng/g (6.35 ng/g; median) and 0.62-3649 ng/g (64.3 ng/g; median), respectively. All the dumpsite samples showed bioavailability for POPs and PAHs. Toxicity equivalent values (TEQs) associated with dioxin-like PCBs and PCDD/Fs from the zones where dumped municipal solid wastes were collected from electronic-waste/IT-corridor/port areas and toxic PAHs from the zone receiving wastes from the industrial corridor of the city were higher than the soil permissible limit prescribed by the World Health Organization.Despite mineral wool waste is only a small fraction of total construction and demolition waste (CDW) by mass, it requires large transportation and landfilling capacities due to its low bulk density, and its utilization remains low compared to other CDW types. It is essential to understand the physical and chemical properties of this waste fraction in order to utilize it, e.g. as fiber reinforcement in composites or as supplementary cementitious material. Here, we provide a chemical and physical characterization of 15 glass wool and 12 stone wool samples of different ages collected from various locations across Europe. In addition, the chemical compositions of 61 glass and stone wool samples obtained from the literature are presented. Glass wool samples show little variation in their chemical composition, which resembles the composition of typical soda-lime silicate glass. Stone wool presents a composition similar to basaltic glass but with variability between samples in terms of calcium, magnesium, and iron content. Potentially toxic elements, such as Cr, Ba, and Ni, are present in mineral wools, but in low concentrations ( less then 0.2%). Both wool types contain organic resin, which may decompose into smaller molecular fragments and ammonia upon heating or contact with alkaline solution. Mineral wool wastes have relatively similar length and width distributions, despite the age and type of the mineral wool. Overall, both mineral wool waste types have homogenous chemical and physical properties as compared to many other mineral wastes which makes their utilization as a secondary raw material promising.Persistent organic pollutants such as brominated flame retardants represent a major problem in the end-of-life of polymer materials. This study investigates the extraction of brominated flame retardants (BFR) from real waste electrical and electronic equipment (WEEE) using supercritical carbon dioxide (sc-CO2). Sc-CO2 is a non-toxic solvent which possesses intermediate properties between liquids and gases which confer it high diffusivity and solubility. A batch of WEEE-derived acrylonitrile-butadienestyrene (ABS) was first characterized to determine its bromine and BFR composition which was found to be four times higher than the regulation limit set in 2019. Then, different parameters of the sc-CO2 process such as temperature, pressure, granulometry and the use of a co-solvent were studied to estimate the effect of each one on the BFR extraction efficiency. With the view to determine the recyclability of the treated polymer, the impact of the extraction process on the polymer material was also studied by Thermogravimetric Analysis (TGA), Differential Scanning Calorimetry (DSC) and Size Exclusion Chromatography (SEC). Selleck IACS-10759 The extraction process performed on less then 500 µm particle size sample at 40 °C and 500 bars during 6 h and using ethanol as a co-solvent allowed to remove 43.5 ± 0.9% of bromine, which was the maximum extraction rate obtained. Sc-CO2 extraction was found to be an efficient technique to remove tetrabromobisphenol A (TBBPA) but the tested conditions did not allow to remove enough polybromodiphenylethers (PBDE) to satisfy the regulation. Sc-CO2 process seems to be a promising pre-treatment method prior to mechanical recycling as no degradation effect on the polymer matrix was observed.Head and neck cancer (HNC) is the fifth most frequent cancer worldwide and associated with significant morbidity. Along with clinical examination and endoscopic evaluation, imaging plays an important role in pre- and posttherapeutic evaluation of patients with HNC. Cross-sectional Imaging techniques such as computed tomography (CT), magnetic resonance imaging (MRI) and positron emission tomography / computed tomography (PET/CT) are routinely used in the assessment of these patients. This review provides an overview of the various cross-sectional imaging modalities used in the evaluation of HNC and will give a short summary of the latest imaging technologies regarding head and neck cancer diagnosis.